Room temperature hydrophosphination using a simple iron salen pre-catalyst.
نویسندگان
چکیده
Phosphines are fundamentally important to the fine chemicals, pharmaceutical and agrochemical industries. Reported is the first example of alkene hydrophosphination using a designed iron pre-catalyst which yields the anti-Markovnikov products in high yield at room temperature. The phosphine products are excellent pro-ligands for Fe-catalyzed Negishi cross-coupling.
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عنوان ژورنال:
- Chemical communications
دوره 50 81 شماره
صفحات -
تاریخ انتشار 2014